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Catalytic Combustion of Propionaldehyde over Alumina-Supported Manganese Oxides KCI 등재

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한국냄새환경학회지 (Journal of Korean Society of Odor Research and Engineering)
한국냄새환경학회 (Korean Society Of Odor Research And Engineering)
초록

In this study, the catalytic combustion of propionaldehyde, which is an Offensive Odorant Substance assigned by the Korean Ministry of Environment (KMOE), over alumina-supported manganese oxide (Mn/Al2 O3) catalysts was investigated. The combustion reaction was carried out in a fixed-bed reactor at the temperature range of 200 ∼340 ℃. Mn/Al2O3 catalysts with Mn loadings ranging from 3.9 to 18.3 wt.% were prepared by impregnation method. The physicochemical characteristics of the catalysts were analyzed by X-Ray Diffraction (XRD), Scanning Electronic Microscopy (SEM) and Brunauer-Emmett-Teller (BET). The Mn crystalline phases of the Mn/Al2O3 catalysts were identified as α-Mn2O3 and β-MnO2. Mn oxides were covered on γ-Al2O3 supports with an average diameter of around 1 μm. With the increase of Mn loadings, the BET surface areas, pore volumes and average pore diameters of the Mn/Al2O3 catalysts decreased. The catalytic activities of Mn/Al2O3 catalysts increased as the Mn loading was increased from 3.9 wt.% to 18.3 wt.%. The catalyst with 18.3 wt.% Mn loading was able to achieve 100% propionaldehyde conversion at 260 ℃. For the same temperature, a lower Gas Hourly Space Velocity (GHSV) and a lower propionaldehyde concentration promote the complete combustion of propionaldehyde.

저자
  • Yi Liu(Department of Civil & Environmental Engineering, Chonnam National University)
  • Zhong-Kun Ma(Department of Civil & Environmental Engineering, Chonnam National University)
  • Seong-Gyu Seo(Department of Civil & Environmental Engineering, Chonnam National University) Corresponding author