Thermal spray coatings and organic coatings are often individually used in corrosion protection of steel structures. Duplex coating systems of thermally sprayed metal coating combination with organic coating represent a new generic type of coatings on offshore steel structures under the highly corrosive environments. In this study, weathering test were carried out on four types of duplex coated specimens; thermally sprayed metals of zinc, zinc-aluminum alloy, aluminum and aluminum-magnesium alloy in combination with painting of acrylic urethane. From the test results, weathering performance of the duplex coating systems were evaluated.