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Hydrogen Production Through Catalytic Dehydrogenation of Decalin over Pt/C Catalyst Using Activated Carbon Aerogel KCI 등재 SCOPUS

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한국재료학회지 (Korean Journal of Materials Research)
한국재료학회 (Materials Research Society Of Korea)
초록

To improve its textural properties as a support for platinum catalyst, carbon aerogel was chemically activated with KOH as a chemical agent. Carbon-supported platinum catalyst was subsequently prepared using the prepared carbon supports(carbon aerogel(CA), activated carbon aerogel(ACA), and commercial activated carbon(AC)) by an incipient wetness impregnation. The prepared carbon-supported platinum catalysts were applied to decalin dehydrogenation for hydrogen production. Both initial hydrogen evolution rate and total hydrogen evolution amount were increased in the order of Pt/CA < Pt/AC < Pt/ACA. This means that the chemical activation process served to improve the catalytic activity of carbon-supported platinum catalyst in this reaction. The high surface area and the well-developed mesoporous structure of activated carbon aerogel obtained from the activation process facilitated the high dispersion of platinum in the Pt/ACA catalyst. Therefore, it is concluded that the enhanced catalytic activity of Pt/ACA catalyst in decalin dehydrogenation was due to the high platinum surface area that originated from the high dispersion of platinum.

목차
Abstract
 1. Introduction
 2. Experimental Procedure
 3. Results and Discussion
 4. Conclusion
 Acknowledgements
 References
저자
  • Gihoon Lee(Department of Chemical Engineering, Myongji University)
  • Ji Yeon Kang, Yeojin(Department of Chemical Engineering, Myongji University)
  • Yeojin Jeong(Department of Chemical Engineering, Myongji University) | Yeojin Jeong and
  • Ji Chul Jung(Department of Chemical Engineering, Myongji University) Corresponding author