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Promoting Effect of MgO in the Photodegradation of Methylene Blue Over MgO/MWCNT/TiO2 Photocatalyst KCI 등재 SCOPUS

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한국재료학회지 (Korean Journal of Materials Research)
한국재료학회 (Materials Research Society Of Korea)
초록

For the present paper, we prepared MgO/MWCNT/TiO2 photocatalyst by using multi-walled carbon nanotubes(MWCNTs) pre-oxidized by m-chlorperbenzoic acid (MCPBA) with magnesium acetate tetrahydrate (Mg(CH2COO)2·4H2O)and titanium n-butoxide (TiOC(CH3)34) as magnesium and titanium precursors. The prepared photocatalyst was analyzed byX-ray diffraction (XRD), scanning electron microscopy (SEM) and energy dispersive X-ray (EDX) analysis. The decompositionof methylene blue (MB) solution was determined under irradiation of ultraviolet (UV) light. The XRD results show that theMgO/MWCNT/TiO2 photocatalyst have cubic MgO structure and anatase TiO2 structure. The porous structure and the TiO2agglomerate coated on the MgO/MWCNT composite can be observed in SEM images. The Mg, O, Ti and C elements can bealso observed in MgO/MWCNT/TiO2 photocatalyst from EDX results. The results of photodegradation of MB solution under UVlight show that the concentration of MB solution decreased with an increase of UV irradiation time for all of the samples. Also,the MgO/MWCNT/TiO2 photocatalyst has the best photocatalytic activity among these samples. It can be considered that theMgO/MWCNT/TiO2 photocatalyst had a combined effect, the effect of MWCNT, which could absorb UV light to create photo-induced electrons (e−), and the electron trapping effect of MgO, which resulted in an increase of the photocatalytic activity of TiO2.

저자
  • Chen, Ming-Liang
  • Zhang, Feng-Jun | Zhang, Feng-Jun
  • Oh, Won-Chun | Oh, Won-Chun