The present study concerns a measurement of porosity at the nano-fibre interface in concrete. Concrete cast with a centrally located nano-fibre (Ø0.39 × 15.0 mm) was segmented for microscopic observation at a bascattered electron (BSE) image. As a result, it was found that the pores generated in the vicinity of the nano-fibre ranged from 5.40 to 11.45%, equivalent to 0.51 - 1.08% of air void in a bulk concrete.