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마이크로리액터를 이용한 전구체 유속에 따른 CdSe/ZnS 양자점의 광학특성 KCI 등재

Optical Characteristics of CdSe/ZnS Quantum Dot with Precursor Flow Rate Synthesized by using Microreactor

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한국분말야금학회지 (Journal of Korean Powder Metallurgy Institute)
한국분말재료학회(구 한국분말야금학회) (Korean Powder Metallurgy Institute)
초록

High-quality colloidal CdSe/ZnS (core/shell) is synthesized using a continuous microreactor. The particle size of the synthesized quantum dots (QDs) is a function of the precursor flow rate; as the precursor flow rate increases, the size of the QDs decreases and the band gap energy increases. The photoluminescence properties are found to depend strongly on the flow rate of the CdSe precursor owing to the change in the core size. In addition, a gradual shift in the maximum luminescent wave (λmax) to shorter wavelengths (blue shift) is found owing to the decrease in the QD size in accordance with the quantum confinement effect. The ZnS shell decreases the surface defect concentration of CdSe. It also lowers the thermal energy dissipation by increasing the concentration of recombination. Thus, a relatively high emission and quantum yield occur because of an increase in the optical energy emitted at equal concentration. In addition, the maximum quantum yield is derived for process conditions of 0.35 ml/min and is related to the optimum thickness of the shell material.

목차
1. 서 론
2. 실험방법
3. 결과 및 고찰
4. 결 론
감사의 글
References
저자
  • 박지영(한국생산기술연구원 한국희소금속산업기술센터, 한양대학교 융합화학공학과) | Ji Young Park
  • 정다운(한국생산기술연구원 한국희소금속산업기술센터) | Da-Woon Jeong
  • 주원(한국생산기술연구원 한국희소금속산업기술센터) | Won Ju
  • 서한욱(한국생산기술연구원 한국희소금속산업기술센터) | Han Wook Seo
  • 좌용호(한양대학교 융합화학공학과) | Yong-Ho Choa
  • 김범성(한국생산기술연구원 한국희소금속산업기술센터, 과학기술연합대학원대학교 희소소재 및 반도체 패키징 공학) | Bum Sung Kim Corresponding author