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Kinetics and Equilibrium Isotherm Studies for the Aqueous Lithium Recovery by Various Type Ion Exchange Resins KCI 등재 SCOPUS

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한국재료학회지 (Korean Journal of Materials Research)
한국재료학회 (Materials Research Society Of Korea)
초록

The characteristics of aqueous lithium recovery by ion exchange were studied using three commercial cation exchange resins: CMP28 (porous type strong acid exchange resin), SCR-B (gel type strong acid exchange resin) and WK60L (porous type weak acid exchange resin). CMP28 was the most effective material for aqueous lithium recovery; its performance was even enhanced by modifying the cation with K+. A comparison to Na+ and H+ form resins demonstrated that the performance enhancement is reciprocally related to the electronegativity of the cation form. Further kinetic and equilibrium isotherm studies with the K+ form CMP28 showed that aqueous lithium recovery by ion exchange was well fitted with the pseudo-second-order rate equation and the Langmuir isotherm. The maximum ion exchange capacity of aqueous lithium recovery was found to be 14.28 mg/g and the optimal pH was in the region of 4-10.

목차
1. Introduction
 2. Experimental
 3. Results and Discussion
  3.1 Effect of Resin Type
  3.2 Effect of Lithium Ion Concentration
  3.3 Kinetics
  3.4 Equilibrium Isotherm
  3.5 Effect of pH
 4. Conclusion
 References
저자
  • Yong Sun Won(Department of Chemical Engineering, Pukyong National University)
  • Hae-na You(Department of Chemical Engineering, Pukyong National University)
  • Min-Gyu Lee(Department of Chemical Engineering, Pukyong National University) Corresponding author