In this study, the effect of temperature effect of the rubber matrix filled with nano sized silica particles composites with silica volume fraction of 19–25% was investigated by the Charpy impact test. The Charpy impact test was conducted in the temperature range from –40°C to 0°C. The critical energy release rate GIC of the rubber matrix composites filled with nano sized silica particles was considerably affected by temperature and it was shown that the maximum value was appeared at higher temperature between temperature tested and it was shown that the value of GIC increases as temperature tested increases. The major fracture mechanisms were matrix deformation, silica particle debonding and delamination, microcrack between particles and matrix, and/or pull out between particles and matrix which is ascertained by SEM photographs of Charpy impact surfaces fracture.