In this paper, internal thermal stresses of the cementitious matrix were evaluated by incorporating polypropylene fibers. By using the temperature heating method specified in KS F 2257-1, the temperatures by a depth were measured. Thermal stress was calculated based on Kodur's thermal stress formula. Different thermal stress behaviors were observed depending on amount of PP fiber. Thas, it will become fundamental data to analyze the thermal stresses behavior of structure members subjected to higher temperature.