Recently, the use of duplex stainless steel which has a two-phase microstructure consisting of grains of ferritic and austenitic stainless steel has been increased in a variety of industrial fields. Especially, STS329FLD with lower nickel content and higher yield strength compared with austenitic stainless steel has been developed. In this paper, experiments have been conducted to investigate the structural behaviors of single shear duplex stainless steel(STS329FLD) bolted connection with four bolts. Specimens with relatively long end distance failed by block shear fracture accompanied with curling (out-of-plane deformation) and the curling reduced the ultimate strength.