A coating system derived from the combination of a sodium and a potassium water glass was developed to apply for steel in oxidizing and humidity environments at elevated temperature. Parameters such as filler volume, viscosity or coating thickness were varied to optimize the coatings. The coated specimens were investigated by TGA, SEM/EDS, and XRD to clarify the microstructure morphology and anti-oxidation behavior. Finally, oxidation tests, adhesion tests, thermal shock resistance tests and humidity resistance tests were performed to evaluate the performance of developed coating.