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Study on Decomposition Characteristics of Organochlorine Pesticides Using Incineration Reaction Reactor

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  • URLhttps://db.koreascholar.com/Article/Detail/342978
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한국폐기물자원순환학회 (Korea Society Of Waste Management)
초록

Annex A and Annex B of the Stockholm Convention define POPs as unintentional releases to Annex C, as well as organochlorine pesticides, polychlorinated biphenyls and hexachlorobenzen which are intentionally produced and used. These pesticides are very stable in the atmosphere due to insecticides, fungicides, herbicides, etc., and are likely to accumulate in living organisms due to residues in crops. There are 15 substances listed in POPs. These materials are widely used due to their high chemical stability, low solubility in water, high volatility, strong insecticidal effect and relatively low production costs. Aldrin-containing pesticides are known to have a combustion method for incineration in a chemical incinerator equipped with a reheat-burner device and a gas scrubber, and a solidification isolation method for solidifying and filling with cement mixed with a combustible material in waste treatment. In the case of solid-phase pesticides, HCB was 421.8 ng/g, Endosolfan-2 73.044 ng/g, PeCB 53.972 ng/g and Endosolfan-1 43.649 ng/g. In the case of liquid pesticides, HCB concentration was the highest at 167.489 ng/g similar to that of the solid phase, followed by PeCB at 23.462 ng/g. B-HCH, g-HCH, d-HCH and the like were detected as a small amount of other substances. It is judged that it is not necessary to set separate operating conditions or preventive facility standards since the material is decomposed sufficiently at 850℃ or more. However, considering the possibility of dioxin or unintentional persistent organic pollutants, it is considered appropriate to operate at above 1,100℃.

저자
  • Y. S. Yoon(Waste-to-Energy Research Division, Environmental Resources Research Department, NIER)
  • E. H. Kwon(Waste-to-Energy Research Division, Environmental Resources Research Department, NIER)
  • J. S. Bae(Waste-to-Energy Research Division, Environmental Resources Research Department, NIER)
  • T. W. Jeon(Waste-to-Energy Research Division, Environmental Resources Research Department, NIER)
  • S. K. Shin(Waste-to-Energy Research Division, Environmental Resources Research Department, NIER)