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TPC 가교를 통한 CA 막의 화학적, 물리적 성질 개선

Improvement of chemical and physical properties of cellulose acetate membrane through cross-linking using terephthaloyl chloride

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  • URLhttps://db.koreascholar.com/Article/Detail/344375
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한국막학회 (The Membrane Society Of Korea)
초록

Cellulose acetate (CA) has been used for microfiltration/ultrafiltration applications because of its good solubility in common solvents. However, it is sensitive to chemical and physical degradation. Therefore, in this study, cellulose acetate was crosslinked with terephthaloyl chloride (TPC) in dimethylacetamide (DMAc) solution to complement these weakness. Cross-linking was confirmed by increasing in dope solution viscosity and FT-IR. To indicate the chemical resistance, weight loss was observed after the cross-linked CA membranes were immersed in ethanol, hexane, acetone and DMAc solvent for 24h. The physical properties were evaluated by the tensile strength. In the result of experience, effect of the degree of cross-linking by increasing of the concentration of TPC improved the chemical and physical properties of CA.

저자
  • 조형준(연세대학교 화학생명공학과) | Hyung Jun Jo
  • 이주성(연세대학교 화학생명공학과) | Ju Sung Lee
  • 서진아(연세대학교 화학생명공학과) | Jin Ah Seo
  • 민병렬(연세대학교 화학생명공학과) | ByoungRyul Min