Membrane application for CO2 capture is competing with other methods such as amine absorption or absorbent, by reasons of low energy and cost effect. Though membrane separation is promising technology, there exists critical challenge: ‘the upper bound.’ Most of researches have focused on improving gas transport properties of selective layer, but we recognized the importance of membrane support layer shich highly affects affinity with coating layer. Here we adjusted several fabrication conditions for highly porous PAN membrane by NIPS method; concentration, temperature, and additive. In this study, experimental results regarding porosity and pore size, are compared to theoretical dusty-gas model. Moreover, we prepared composite membrane and compared fabricated membrane with commercial one in terms of gas permeance and selectivity.