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수압과 금속염을 활용한 세퍼레이터용 나노다공성 셀룰로오스 아세테이트 제조

Preparation of nanoporous cellulose acetate by water pressure and metal salt for applications to separator

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한국막학회 (The Membrane Society Of Korea)
초록

The straight nanopores in cellulose acetate (CA) polymers for battery gel separators were generated by utilizing both Ni(NO3)2·6H2O and water pressure. When polymer film was exposed to water pressure, the continuous nanopores were generated after complexing with Ni(NO3)2·6H2O. These results could be explained by that polymer chains were weakened because of the plasticization effect of the Ni(NO3)2·6H2O incorporated into the CA. The well controlled CA membrane after water pressure treatment enabled fabrication of highly reliable cell by utilizing 2032-type coin cell structure. The resulting cell performance exhibited both the effect of the physical morphology of CA separator and the chemical interaction of electrolyte with CA polymer which facilitates the Li-ion in the cell.

저자
  • 강상욱(상명대학교 화학에너지공학과) | Sang Wook Kang