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산화환원반응용 백금 촉매 지지체를 위한 질소 도핑된 단백질계 탄소의 제조 KCI 등재 SCOPUS

Synthesis of Nitrogen Doped Protein Based Carbon as Pt Catalysts Supports for Oxygen Reduction Reaction

이영근, 안건형, 안효진
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한국재료학회지 (Korean Journal of Materials Research)
한국재료학회 (Materials Research Society Of Korea)
초록

Nitrogen (N)-doped protein-based carbon as platinum (Pt) catalyst supports from tofu for oxygen reduction reactions are synthesized using a carbonization and reduction method. We successfully prepare 5 wt% Pt@N-doped protein-based carbon, 10 wt% Pt@N-doped protein-based carbon, and 20 wt% Pt@N-doped protein-based carbon. The morphology and structure of the samples are characterized by field emission scanning electron microscopy and transmission electron micro scopy, and crystllinities and chemical bonding are identified using X-ray diffraction and X-ray photoelectron spectroscopy. The oxygen reduction reaction are measured using a linear sweep voltammogram and cyclic voltammetry. Among the samples, 10 wt% Pt@N-doped protein-based carbon exhibits exellent electrochemical performance with a high onset potential of 0.62 V, a high E1/2 of 0.55 V, and a low ΔE1/2= 0.32 mV. Specifically, as compared to the commercial Pt/C, the 10 wt% Pt@N-doped proteinbased carbon had a similar oxygen reduction reaction perfomance and improved electrochemical stability.

키워드
protein based carbonoxygen reduction reactionnitrogen doping.
목차
1. 서 론
 2. 실험 방법
 3. 결과 및 고찰
 4. 결 론
 References
저자
  • 이영근(서울과학기술대학교 신소재공학과) | Young-geun Lee
  • 안건형(서울과학기술대학교 의공학 바이오소재 융합 협동과정 신소재공학 프로그램) | Geon-hyeong An
  • 안효진(서울과학기술대학교 신소재공학과, 서울과학기술대학교 의공학 바이오소재 융합 협동과정 신소재공학 프로그램) | Hyo-Jin Ahn Corresponding author