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산화환원반응용 백금 촉매 지지체를 위한 질소 도핑된 단백질계 탄소의 제조 KCI 등재 SCOPUS

Synthesis of Nitrogen Doped Protein Based Carbon as Pt Catalysts Supports for Oxygen Reduction Reaction

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  • URLhttps://db.koreascholar.com/Article/Detail/345665
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한국재료학회지 (Korean Journal of Materials Research)
한국재료학회 (Materials Research Society Of Korea)
초록

Nitrogen (N)-doped protein-based carbon as platinum (Pt) catalyst supports from tofu for oxygen reduction reactions are synthesized using a carbonization and reduction method. We successfully prepare 5 wt% Pt@N-doped protein-based carbon, 10 wt% Pt@N-doped protein-based carbon, and 20 wt% Pt@N-doped protein-based carbon. The morphology and structure of the samples are characterized by field emission scanning electron microscopy and transmission electron micro scopy, and crystllinities and chemical bonding are identified using X-ray diffraction and X-ray photoelectron spectroscopy. The oxygen reduction reaction are measured using a linear sweep voltammogram and cyclic voltammetry. Among the samples, 10 wt% Pt@N-doped protein-based carbon exhibits exellent electrochemical performance with a high onset potential of 0.62 V, a high E1/2 of 0.55 V, and a low ΔE1/2= 0.32 mV. Specifically, as compared to the commercial Pt/C, the 10 wt% Pt@N-doped proteinbased carbon had a similar oxygen reduction reaction perfomance and improved electrochemical stability.

목차
1. 서 론
 2. 실험 방법
 3. 결과 및 고찰
 4. 결 론
 References
저자
  • 이영근(서울과학기술대학교 신소재공학과) | Young-geun Lee
  • 안건형(서울과학기술대학교 의공학 바이오소재 융합 협동과정 신소재공학 프로그램) | Geon-hyeong An
  • 안효진(서울과학기술대학교 신소재공학과, 서울과학기술대학교 의공학 바이오소재 융합 협동과정 신소재공학 프로그램) | Hyo-Jin Ahn Corresponding author