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미세유체반응기를 이용한 core/shell 연속 합성 시스템을 이용한 CdSe/ZnS 양자점 합성 및 분석 KCI 등재

Synthesis and analysis CdSe/ZnS quantum dot with a Core/shell Continuous Synthesis System Using a Microfluidic Reactor

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한국분말야금학회지 (Journal of Korean Powder Metallurgy Institute)
한국분말재료학회(구 한국분말야금학회) (Korean Powder Metallurgy Institute)
초록

Core/shell CdSe/ZnS quantum dots (QDs) are synthesized by a microfluidic reactor-assisted continuous reactor system. Photoluminescence and absorbance of synthesized CdSe/ZnS core/shell QDs are investigated by fluorescence spectrophotometry and online UV-Vis spectrometry. Three reaction conditions, namely; the shell coating reaction temperature, the shell coating reaction time, and the ZnS/CdSe precursor volume ratio, are combined in the synthesis process. The quantum yield of the synthesized CdSe QDs is determined for each condition. CdSe/ZnS QDs with a higher quantum yield are obtained compared to the discontinuous microfluidic reactor synthesis system. The maximum quantum efficiency is 98.3% when the reaction temperature, reaction time, and ZnS/CdSe ratio are 270℃, 10 s, and 0.05, respectively. Obtained results indicate that a continuous synthesis of the Core/shell CdSe/ZnS QDs with a high quantum efficiency could be achieved by isolating the reaction from the external environment.

목차
Abstract
 1. 서 론
 2. 실험 방법
  2.1. CdSe, ZnS 전구체 제조
  2.2. CdSe/ZnS 양자점 합성
 3. 결과 및 고찰
 4. 결 론
 References
저자
  • 홍명환(고등기술연구원 신소재공정센터) | Myung Hwan Hong
  • 주소영(고등기술연구원 신소재공정센터) | So Young Joo
  • 강이승(고등기술연구원 신소재공정센터) | Lee-Seung Kang
  • 이찬기(고등기술연구원 신소재공정센터) | Chan Gi Lee Corresponding Author