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울산산업공단에서 배출되는 coal fly ash로 합성한 제올라이트를 폴리슬폰으로 고정화하여 제조한 PS-FZ 비드의 Sr 및 Cu 제거 특성 KCI 등재

Removal Characteristics of Sr and Cu Ions using PS-FZ Beads fabricated by Immobilization of Zeolite prepared from Coal Fly Ash from an Ulsan Industrial Complex with Polysulfone

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한국환경과학회지 (Journal of Environmental Science International)
한국환경과학회 (The Korean Environmental Sciences Society)
초록

Zeolite (FZ) prepared using coal fly ash from an Ulsan industrial complex was immobilized with polysulfone (PS) to fabricate PS-FZ beads. The prepared PS-FZ beads were characterized by scanning electron microscopy and Fourier transform infrared spectroscopy. The optimum ratio for preparing PS-FZ beads was 1 g of PS to 2 g of FZ. The removal efficiencies of Sr and Cu ions by the PS-FZ beads increased as the solution pH increased and nearly reached a plateau at pH 4. A pseudo-second-order model morel fit the adsorption kinetics of both ions by the PS-FZ beads better than a pseudo-first-order model. The Langmuir isotherm model fit the equilibrium data well. The maximum adsorption capacities calculated from the Langmuir isotherm model were 46.73 mg/g and 62.54 mg/g for the Sr and Cu ions, respectively. Additionally, the values of thermodynamic parameters such as free energy (ΔG˚), enthalpy (ΔH˚) and entropy (ΔS˚) were determined. The results implied that the prepared PS-FZ beads could be interesting an alternative material for Sr and Cu ion removal.

목차
Abstract
 1. 서 론
 2. 재료 및 방법
  2.1. 재료
  2.2. PS-FZ 흡착제 제조
  2.3. 실험 방법
 3. 결과 및 고찰
  3.1. PS-FZ 흡착체의 제조 조건
  3.2. PS-FZ의 특성 분석
  3.3. 초기 농도에 따른 흡착량
  3.4. 흡착속도모델
  3.5. 초기 pH에 따른 흡착량 변화
  3.6. 흡착등온선
  3.7. 열역학적 해석
 4. 결 론
 REFERENCES
저자
  • 감상규(제주대학교 환경공학과, Department of Environmental Engineering, Jeju National University) | Sang-Kyu Kam
  • 이창한(부산가톨릭대학교 환경행정학과, Department of Environmental Administration, Catholic University of Pusan) | Chang-Han Lee
  • 정갑섭(동명대학교 식품영양학과, Department of Food Science & Nutritional, Tongmyong University) | Kap-Seop Jeong
  • 이민규(부경대학교 화학공학과, Department of Chemical Engineering, Pukyong National University) | Min-Gyu Lee Corresponding author