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Control of Airborne Organic Pollutants Using Plug-Flow Reactor Coated With Carbon Material-Titania Mixtures Under Visible-Light Irradiation KCI 등재

Wan-Kuen Jo, Hyun-Jung Kang, Mo-Keun Kim
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한국환경과학회지 (Journal of Environmental Science International)
한국환경과학회 (The Korean Environmental Sciences Society)
초록

Graphene oxide (GO)-titania composites have emerged as an attractive heterogeneous photocatalyst that can enhance the photocatalytic activity of TiO2 nanoparticles owing to their potential interaction of electronic and adsorption natures. Accordingly, TiO2-GO mixtures were synthesized in this study using a simple chemical mixing process, and their heterogeneous photocatalytic activities were investigated to determine the degradation of airborne organic pollutants (benzene, ethyl benzene, and o-xylene (BEX)) under different operational conditions. The Fourier transform infrared spectroscopy results demonstrated the presence of GO for the TiO2-GO composites. The average efficiencies of the TiO2-GO mixtures for the decomposition of each component of BEX determined during the 3-h photocatalytic processes were 26%, 92%, and 96%, respectively, whereas the average efficiencies of the unmodified TiO2 powder were 3%, 8%, and 10%, respectively. Furthermore, the degradation efficiency of the unmodified TiO2 powder for all target compounds decreased during the 3-h photocatalytic processes, suggesting a potential deactivation even during such a short time period. Two operational conditions (air flow entering into the air-cleaning devices and the indoor pollution levels) were found to be important factors for the photocatalytic decomposition of BEX molecules. Taken together, these results show that a TiO2-GO mixture can be applied effectively for the purification of airborne organic pollutants when the operating conditions are optimized.

키워드
Heterogeneous photocatalystAirborne organic pollutantGraphene-TiO2 mixtureFTIR spectra
목차
Abstract
 1. Introduction
 2. Methodology
 3. Results and discussion
 4. Conclusions
 References
저자
  • Wan-Kuen Jo(Department of Environmental Engineering, Kyungpook National University) Corresponding author
  • Hyun-Jung Kang(Department of Environmental Engineering, Kyungpook National University)
  • Mo-Keun Kim(GyeongSangBukdo Government Public Institute of Health and Environment)