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Control of Airborne Organic Pollutants Using Plug-Flow Reactor Coated With Carbon Material-Titania Mixtures Under Visible-Light Irradiation KCI 등재

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한국환경과학회지 (Journal of Environmental Science International)
한국환경과학회 (The Korean Environmental Sciences Society)
초록

Graphene oxide (GO)-titania composites have emerged as an attractive heterogeneous photocatalyst that can enhance the photocatalytic activity of TiO2 nanoparticles owing to their potential interaction of electronic and adsorption natures. Accordingly, TiO2-GO mixtures were synthesized in this study using a simple chemical mixing process, and their heterogeneous photocatalytic activities were investigated to determine the degradation of airborne organic pollutants (benzene, ethyl benzene, and o-xylene (BEX)) under different operational conditions. The Fourier transform infrared spectroscopy results demonstrated the presence of GO for the TiO2-GO composites. The average efficiencies of the TiO2-GO mixtures for the decomposition of each component of BEX determined during the 3-h photocatalytic processes were 26%, 92%, and 96%, respectively, whereas the average efficiencies of the unmodified TiO2 powder were 3%, 8%, and 10%, respectively. Furthermore, the degradation efficiency of the unmodified TiO2 powder for all target compounds decreased during the 3-h photocatalytic processes, suggesting a potential deactivation even during such a short time period. Two operational conditions (air flow entering into the air-cleaning devices and the indoor pollution levels) were found to be important factors for the photocatalytic decomposition of BEX molecules. Taken together, these results show that a TiO2-GO mixture can be applied effectively for the purification of airborne organic pollutants when the operating conditions are optimized.

목차
Abstract
 1. Introduction
 2. Methodology
 3. Results and discussion
 4. Conclusions
 References
저자
  • Wan-Kuen Jo(Department of Environmental Engineering, Kyungpook National University) Corresponding author
  • Hyun-Jung Kang(Department of Environmental Engineering, Kyungpook National University)
  • Mo-Keun Kim(GyeongSangBukdo Government Public Institute of Health and Environment)