In this study, reaction model and reactions rate accelerated by o-iodosobenzoate ion(IB⊖) on hydrolysis reaction of p-nitrophenyl valate(NPV) using ethyl tri-octyl ammonium mesylate(ETAMs) for quaternary ammonium salts, the phase transfer catalysis(PTC) reagent, were investigated. The effect of IB⊖ on hydrolysis reaction rate constant of NPV was weak without ETAMs solutions. Otherwise, in ETAMs solutions, the hydrolysis reactions exhibit higher first order kinetics with respect to the nucleophile, IB⊖, and ETAMs, suggesting that reactions are occurring in small aggregates of the three species including the substrate(NPV), whereas the reaction of NPV with OH⊖ is not catalyzed by ETAMs. Different concentrations of NPV were tested to measure the change of rate constants to investigate the effect of NPV as substrate and the results showed that the effect was weak. This means the reaction would be the first order kinetics with respect to the nucleophile. This behavior for the drastic rate-enhancement of the hydrolysis is referred as 'Aggregation complex model' for reaction of hydrophobic organic ester with o-iodosobenzoate ion(IB⊖) in hydrophobic quarternary ammonium salt(ETAMs) solutions.

Abstract
 1. 서 론
 2. 재료 및 방법
  2.1. 실험재료
  2.2. 실험방법
 3. 결과 및 고찰
  3.1. Carbonate buffer 수용액 속에서의 NPV의 가수분해반응
  3.2. 상이동촉매인 ETAMs 수용액 속에서의 NPV의가수분해반응
  3.3. ETAMs 수용액 속에서의 IB⊖에 의해 추진되는 가수분해반응의 모델
  3.4. 새로운 반응에의 응용
 4. 결 론
 참고문헌

• 김정배(계명대학교 환경대학) | Jeung-Bea Kim (Falculty of Environmental Studies, Keimyung University) Corresponding Author