In this research, equilibrium of adsorption and kinetics of As(V) removal were investigated. The coal mine drainage sludge(CMDS) was used as adsorbent. To find out the physical and chemical properties of CMDS, XRD (X-ray diffraction), XRF (X-ray fluorescence spectrometer) analysis were carried out. The CMDS was consist of 70% of goethite and 30% of calcite. From the results, an adsorption mechanism of As(V) with CMDS was dominated by iron oxides. Langmuir adsorption isotherm model was fitted well more than Freundlich isotherm adsorption model. Adsorption capacities of CMDS 1 was not different with CMDS 2 on aspect of amounts of arsenic adsorbed. The maximum adsorption amount of two CMDS were respectively 40.816, 39.682 mg/g. However, the kinetic of two CMDS was different. The kinetic was followed pseudo second order model than pseudo first order model. Concentrations of arsenic in all segments of the polymer in CMDS 2 does not have a constant value, but the rate was greater than the value of CMDS 1. Therefore, CMDS 2, which is containing polymer, is more effective for adsorbent to remove As(V).

Abstract
 1. 서 론
 2. 재료 및 방법
  2.1. 실험재료
  2.2. 실험장치 및 방법
  2.3. 등온흡착실험
  2.4. 동적흡착 실험
 3. 결과 및 고찰
  3.1. 석탄광산배수슬러지(CMDS)의 물리․화학적 특성
  3.2. 등온흡착 실험
  3.3. 동적흡착 연구
 4. 결 론
 참 고 문 헌

• 이세반(고려대학교 건축사회환경공학과) | Seban Lee (Department of Civil Environmental and Architectural Engineering, Korea University)
• 최명찬(고려대학교 건축사회환경공학과) | Mingcan Cui (Department of Civil Environmental and Architectural Engineering, Korea University)
• 장민(한국광해관리공단) | Min Jang (Korea Mine Reclamation Corporation, Institute of Mine Reclamation Technology)
• 문덕현(조선대학교 환경공학과) | Deok Hyun Moon (Department of Environmental Engineering , Chosun University)
• 조윤철(광운대학교 녹색환경에너지대학원) | Yunchul Cho (Graduate School of Green Environment & Energy, Kwangwoon University)
• 김지형(고려대학교 건축사회환경공학과) | Jeehyeong Khim (Department of Civil Environmental and Architectural Engineering, Korea University) Corresponding Author