논문 상세보기
pp.203-210
The batch tests were performed to determine the ratio of Fenton reagent on diesel contaminated soil. The objective of a column test was to determine and optimize the hydrogen peroxide requirements for the remediation of a soil contaminated with diesel fuel. The batch test were done on 5 g diesel contaminated soil containing hydrogen peroxide (35%) and Iron (II) sulfate. The H2O2(g):Fe2+(g) ratio varied 1:0, 30:1, 15:1, 5:1, 1:1, with contact reaction time 120min. Initial diesel concentration were 2,000 mg/kg, 5,000 mg/kg, and 10,000 mg/kg. Average diesel removal from the contaminated soil is 97% after 2hrs. Results of this study showed possible application of without addition of iron source. In column test, treatment of a diesel-contaminated soil (initial diesel concentration: 2,000 mg/kg, 5,000 mg/kg, and 10,000 mg/kg) with hydrogen peroxide (35%) only was containing natural-occurring minerals. The time required for the column test was approximately 90min, 180min, 270min; column length was 5 cm, 10 cm, and 15 cm. The most effective stoichiometry (final diesel conc.: 200~300 mg/kg) of 0.2 g peroxide consumed/mg diesel degraded. Further investigation is required to identify the effect of soil organic matter and soil mineral.
