In this study, zeolite (Z-C1) was synthesized using a fusion/hydrothermal method from coal fly ash. The morphological structures of Z-C1 were confirmed to be highly crystalline with a cubic crystal structure. Exchange capacities of Ca2+ and Mg2+ ions in a single and a mixed solution reached equilibrium within 120 min. The exchange kinetics of these ions were well predicted by the pseudo-second-order rate equation. The exchange isotherms of the Ca2+ and Mg2+ ions matched the Langmuir isotherm better than the Freundlich isotherm. The maximum cation exchange capacities (qm) obtained by the Langmuir isotherm model were 2.11 mmol/g (84.52 mg/L) and 1.13 mmol/g (27.39 mg/L) for the Ca2+ and Mg2+ ions, respectively.