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Electro-Fenton 반응을 이용한 유독성 유기화합물 처리 KCI 등재

Removal of Toxic Organic Compound using Electro-Fenton Reaction

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한국환경과학회지 (Journal of Environmental Science International)
한국환경과학회 (The Korean Environmental Sciences Society)
초록

The feasibility and efficiency of the hydrogen peroxide produced by an electrolysis cell reactor was investigated. From regulating voltages for the given reaction time, the concentration of the hydrogen peroxide was gradually increased with increasing voltages.
Optimal voltage range was found to be 10~15 V. The concentration of hydrogen peroxide was much higher with oxygen gas than without oxygen gas in the cathodic chamber. But there was a little difference in the generating rate of hydrogen peroxide regardless of the presence of nitrogen gas.
Under given conditions, the maximum value of ICE(Instantaneous Current Efficiency) was about 38%, and then current density was 74 mA/cm2. The specific energy consumption was 0.694[㎾h/kg-H2O2]. Since Esp (Specific Energy Consumption)was very little value, It did not demand high energy in this system.
Using the hydrogen peroxide gained in the experiment, Fenton's reaction was conducted and the removal of nitrobenzene, 3-chlorophenol and dye wastewater was studied. This results were very similar to the Fenton's reaction by using commercial hydrogen peroxide.

저자
  • 박상원(계명대학교 환경과학과) | Sang-Won Park Corresponding Author