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질산제조 플랜트 N2O 제거용 촉매기술: 적용위치별 기술옵션 KCI 등재

Catalytic Technologies for Nitric Acid Plants N2O Emissions Control: In-Duct-Dependent Technological Options

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한국환경과학회지 (Journal of Environmental Science International)
한국환경과학회 (The Korean Environmental Sciences Society)
초록

A unit emission reduction of nitrous oxide (N2O) from anthropogenic sources is equivalent to a 310-unit CO2 emission reduction because the N2O has the global warming potential (GWP) of 310. This greatly promoted very active development and commercialization of catalysts to control N2O emissions from large-scale stationary sources, representatively nitric acid production plants, and numerous catalytic systems have been proposed for the N2O reduction to date and here designated to Options A to C with respect to in-duct-application scenarios. Whether or not these Options are suitable for N2O emissions control in nitric acid industries is primarily determined by positions of them being operated in nitric acid plants, which is mainly due to the difference in gas temperatures, compositions and pressures. The Option A being installed in the NH3 oxidation reactor requires catalysts that have very strong thermal stability and high selectivity, while the Option B technologies are operated between the NO2 absorption column and the gas expander and catalysts with medium thermal stability, good water tolerance and strong hydrothermal stability are applicable for this option. Catalysts for the Option C, that is positioned after the gas expander thereby having the lowest gas temperatures and pressure, should possess high deN2O performance and excellent water tolerance under such conditions. Consequently, each deN2O technology has different opportunities in nitric acid production plants and the best solution needs to be chosen considering the process requirements.

목차
Abstract
 1. 서 론
 2. 재료 및 방법
 3. 결과 및 고찰
  3.1. 질산제조 플랜트 공정
  3.2. 질산제조반응과 N2O 배출
  3.3. 질산제조 플랜트에 적용 가능한 deN2O 촉매기술옵션 및 요건
  3.4. 옵션별 deN2O 기술
 4. 결 론
 참 고 문 헌
저자
  • 김문현(대구대학교 환경공학과) | Moon Hyeon Kim (Department of Environmental Engineering, Daegu University) Corresponding author