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과황산의 열적활성화 및 염소계용제의 산화분해 KCI 등재

Oxidation of Chloroethenes by Heat-Activated Persulfate

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한국환경과학회지 (Journal of Environmental Science International)
한국환경과학회 (The Korean Environmental Sciences Society)
초록

Oxidative degradation of chlorinated ethenes was carried out using heat-activated persulfate. The activation rate of persulfate was dependent on the temperature and the activation reaction rate could be explained based on the Arrhenius equation. The activation energy of persulfate was 19.3 kcal/mol under the assumption that the reaction between the sulfate radical and tricholoroethene (TCE) is very fast. Activation could be achieved at a moderate temperature, so that the adverse effects due to high temperature in the soil environment were mitigated. The reaction rate of TCE was directly proportional to the concentration of persulfate, indicating that the remediation rate can be controlled by the concentration of the injected persulfate. The solution was acidized after the oxidation, and this was dependent on the oxidation temperature. The consumption rate of persulfate was high in the presence of the target organic, but the self-decomposition rate became very low as the target was completely removed.

목차
Abstract
 1. 서 론
 2. 재료 및 방법
  2.1. 재료 및 실험방법
  2.2. 분석방법
 3. 결과 및 고찰
  3.1. TCE를 대상으로 한 온도에 따른 과황산 활성화 평가
  3.2. 염소계 에텐(PCE, TCE, 1,2-cis-DCE, 1,2-trans-DCE,1,1-DCE)의 분해특성
  3.3. 과황산의 주입량에 따른 활성화 효율 평가
 4. 결 론
 REFERENCES
저자
  • 장하이롱(안동대학교 환경공학과) | Hailong Zhang (Department of Environmental Engineering, Andong National University)
  • 권희원(안동대학교 환경공학과) | Hee-Won Kwon (Department of Environmental Engineering, Andong National University)
  • 최정학(부산가톨릭대학교 환경공학과) | Jeong-Hak Choi (Department of Environmental Engineering, Catholic University of Pusan)
  • 김영훈(안동대학교 환경공학과) | Young-Hun Kim (Department of Environmental Engineering, Andong National University) Corresponding author