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N2O 분해를 위한 전이금속이 도핑된 메조포러스 실리카 촉매의 합성과 표면 특성에 관한 연구 KCI 등재

Synthesis and Surface Characterization of Transition Metal Doped Mesoporous Silica Catalysts for Decomposition of N2O

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한국환경과학회지 (Journal of Environmental Science International)
한국환경과학회 (The Korean Environmental Sciences Society)
초록

The purpose of this study is to synthesize transition metal doped mesoporous silica catalyst and to characterize its surface in an attempt to decomposition of N2O. Transition metal used to surface modification were Ru, Pd, Cu and Fe concentration was adjusted to 0.05 M. The prepared mesoporous silica catalysts were characterized by X-ray diffraction, BET surface area, BJH pore size, Scanning Electron Microscopy and X-ray fluorescence. The results of XRD for mesoporous silica catalysts showed typical the hexagonal pore system. BET results showed the mesoporous silica catalysts to have a surface area of 537 ∼973 m2/g and pore size of 2∼4 nm. The well-dispersed particle of mesoporous silica catalysts were observed by SEM, the presence and quantity of transition metal loading to mesoporous surface were detected by XRF. The N2O decomposition efficiency on mesoporous silica catalysts were as follow: Ru>Pd>Cu>Fe. The results suggest that transition metal doped mesoporous silica is effective catalyst for decomposition of N2O.

목차
Abstract
 1. 서 론
 2. 재료 및 방법
  2.1. 실험 재료 및 방법
  2.2. N2O 분해 실험 방법 및 장치
 3. 결과 및 고찰
  3.1. 메조포러스 실리카 촉매의 특성분석
  3.2. N2O 분해 효율 평가
 4. 결 론
 참 고 문 헌
저자
  • 이갑두(계명대학교 녹색융합기술연구소) | Kamp-Du Lee (Center for Green & Fusion Technologies, Keimyung University)
  • 노민수(계명대학교 녹색융합기술연구소) | Min-Soo Noh (Center for Green & Fusion Technologies, Keimyung University)
  • 박상원(계명대학교 녹색융합기술연구소) | Sang-Won Park (Center for Green & Fusion Technologies, Keimyung University) Corresponding author