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Sol-Gel법을 이용한 CuxCo3-xO4 산소 발생 촉매의 합성 및 전기화학 특성 분석 KCI 등재 SCOPUS

Electrochemical Analysis of CuxCo3-xO4 Catalyst for Oxygen Evolution Reaction Prepared by Sol-Gel Method

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한국재료학회지 (Korean Journal of Materials Research)
한국재료학회 (Materials Research Society Of Korea)
초록

Transition metal oxide is widely used as a water electrolysis catalyst to substitute for a noble metal catalyst such as IrO2 and RuO2. In this study, the sol-gel method is used to synthesize the CuxCo3-xO4 catalyst for the oxygen evolution reaction (OER),. The CuxCo3-xO4 is synthesized at various calcination temperatures from 250 ℃ to 400 ℃ for 4 h. The CuxCo3- xO4 synthesized at 300 ℃ has a perfect spinel structure without residues of the precursor and secondary phases, such as CuO. The particle size of CuxCo3-xO4 increases with an increase in calcination temperature. Amongst all the samples studied, CuxCo3- xO4, which is synthesized at 300?, has the highest activity for the OER. Its onset potential for the OER is 370 mV and the overpotential at 10 mA/cm2 is 438 mV. The tafel slope of CuxCo3-xO4 synthesized at 300 ℃ has a low value of 58 mV/dec. These results are mainly explained by the increase in the available active surface area of the CuxCo3-xO4 catalyst.

목차
Abstracts
 1. 서 론
 2. 실험 방법
 3. 결과 및 고찰
 4. 결 론
 References
저자
  • 박유세(부산대학교 공과대학 재료공학과) | Yoo Sei Park (School of Materials Science and Engineering, Pusan National University)
  • 정창욱(부산대학교 공과대학 재료공학과) | Changwook Jung (School of Materials Science and Engineering, Pusan National University)
  • 김치호(부산대학교 공과대학 재료공학과) | Chiho Kim (School of Materials Science and Engineering, Pusan National University)
  • 구태우(부산대학교 공과대학 재료공학과) | Taewoo Koo (School of Materials Science and Engineering, Pusan National University)
  • 석창규(부산대학교 공과대학 재료공학과) | Changgyu Seok (School of Materials Science and Engineering, Pusan National University)
  • 권일영(부산대학교 공과대학 재료공학과) | Ilyeong Kwon (School of Materials Science and Engineering, Pusan National University)
  • 김양도(부산대학교 공과대학 재료공학과) | Yangdo Kim (School of Materials Science and Engineering, Pusan National University) Corresponding author