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pp.437-441
A study on the removal of Pb ion from Pb-contaminated soil was carried out, using ex-situ extraction process. Tartaric acid (TA) and iminodiacetic acid sodium salt (IDA) as a washing agent were evaluated as a function of concentration, reaction time, mixing ratio of washing agent and recycling of washing agent. TA showed a better extraction performance than IDA.
The optimum washing condition of TA and IDA were in the ratio of 1 : 15 and 1 : 20 between soil and acid solution during 1 hr reaction. The total concentrations of Pb ion by TA and IDA at three repeated extraction, were 368.8 ppm and 267.5 ppm, respectively.
The recovery of Pb ion from washing solution was achieved by adding calcium hydroxide and sodium sulfide, form the precipitation of lead hydroxide and lead sulfide, and optimum amounts of sodium sulfide and calcium hydroxide were 7 g/ℓ for the TA washing solution and 4 g/ℓ , 5 g/ℓ for the IDA washing solution, respectively. The efficiency of recycle for TA and IDA washing solution were 78.8%, 95.1% and 89.2%, 96.6%, at third extractions under Na2S and Ca(OH)2, respectively.
