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금속산화물 분말의 동결건조 및 수소환원에 의한 Mo-Cu 다공체 제조 KCI 등재

Fabrication of Porous Mo-Cu by Freeze Drying and Hydrogen Reduction of Metal Oxide Powders

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한국분말야금학회지 (Journal of Korean Powder Metallurgy Institute)
한국분말재료학회(구 한국분말야금학회) (Korean Powder Metallurgy Institute)
초록

In this study, porous Mo-5 wt% Cu with unidirectionally aligned pores is prepared by freeze drying of camphene slurry with MoO3-CuO powders. Unidirectional freezing of camphene slurry with dispersion stability is conducted at -25℃, and pores in the frozen specimens are generated by sublimation of the camphene crystals. The green bodies are hydrogen-reduced at 750℃ and sintered at 1000℃ for 1 h. X-ray diffraction analysis reveals that MoO3- CuO composite powders are completely converted to a Mo-and-Cu phase without any reaction phases by hydrogen reduction. The sintered bodies with the Mo-Cu phase show large and aligned parallel pores to the camphene growth direction as well as small pores in the internal walls of large pores. The pore size and porosity decrease with increasing composite powder content from 5 to 10 vol%. The change of pore characteristics is explained by the degree of powder rearrangement in slurry and the accumulation behavior of powders in the interdendritic spaces of solidified camphene.

목차
Abstract
 1. 서 론
 2. 실험방법
 3. 실험결과 및 고찰
 4. 결 론
 References
저자
  • 강현지(서울과학기술대학교 신소재공학과) | Hyunji Kang (Department of Materials Science and Engineering, Seoul National University of Science and Technology)
  • 한주연(서울과학기술대학교 신소재공학과) | Ju-Yeon Han (Department of Materials Science and Engineering, Seoul National University of Science and Technology)
  • 오승탁(서울과학기술대학교 신소재공학과) | Sung-Tag Oh (Department of Materials Science and Engineering, Seoul National University of Science and Technology) Corresponding Author