This study investigates impact damage behavior of a reinforced concrete structure that undergoes both a shock impulsive loading and an impact loading due to the air blast induced from an explosion is performed. Firstly, a pair of multiple loadings are selected from the scenario that an imaginary explosion accident is assumed. The rectangular RC walls strengthened with Glass Fiber Reinforced Polymer (GFRP) are considered as a scheme for retrofitting rectangular RC wall structures subjected to multiple explosive loadings and then the evaluation of the resistant performance against them is presented in comparison with the result of the evaluation of a rectangular RC wall without retrofit. Also, in order to derive the result of the analysis similar to that of real explosion experiments, which require the vast investment and expense for facilities, the constitutive equation and the equation of state (EOS) which can describe the real impact and shock phenomena accurately are included with them. In addition, the numerical simulations of two rectangular RC walls are achieved using AUTODYN-3D, an explicit analysis program, in order to prove the retrofit performance of a GFRP-strengthened rectangular RC wall.