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Removal efficiency of dissolved sulfide in sewage wastewater by chemical oxidants and coagulants

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실내환경 및 냄새 학회지 (Journal of Odor and Indoor Environment)
한국냄새환경학회 (Korean Society Of Odor Research And Engineering)
초록

Sulfide dissolved in wastewater is a potential source of hydrogen sulfide. Hydrogen sulfide is an odorous substance that causes civil complaints and is a dangerous substance that threatens the corrosion of structures and the safety and health of workers. The removal efficiencies of the chemical oxidant and the coagulants were compared to evaluate the removal of dissolved sulfide. Since the effectiveness may vary depending on the characteristics of the wastewater, water was used as a control, and 5 mg/L of dissolved sulfide was dissolved in water and sewage wastewater. When oxidant was used, the results showed a high sulfide removal rate in sewage wastewater than water, and the removal efficiency was enhanced with increasing oxidant concentration. Sulfide removal efficiencies after one hour after injecting oxidants H2O2, NaOCl, NaClO2 to sewage wastewater were 70%, 90%, and 100%, respectively. After the oxidants were administered four times, the removal was 90%, 100%, and 100%, respectively. In the case of sulfide removal with the oxidizing agent, the removal efficiency was NaClO2, NaOCl, H2O2 (highest - lowest). NaClO2 showed 100% removal efficiency within 10 minutes under all conditions (A condition, B condition), making it the most sewage effective agent in this study. In the case of the coagulants, 100% of the sulfides dissolved in water were removed in the first 10 minutes under all conditions. In sewage wastewater, FeCl2 and FeSO4 also showed 100% removal efficiency under all conditions after one hour, and FeCl3 showed 90% and 99% removal rates under A and B conditions, respectively. That is, the monovalent iron coagulants (FeCl2, FeSO4) were found to be somewhat more effective in the removal of sulfides in sewage wastewater than the divalent iron (FeCl3) coagulants. When the sulfides were removed with coagulants, FeCl2 had the highest removal efficiency followed by FeSO4 and FeCl3. Moreover, it was found that NaClO2 has the best reaction efficiency at the minimum reaction time and the reaction concentration.

목차
Abstract
1. 서 론
2. 연구방법
3. 결 과
4. 고 찰
5. 결 론
References
저자
  • 김지슬(수원대학교 환경에너지공학과) | Ji Seul Kim (Dept. of Environmental and Energy Engineering, The University of Suwon)
  • 조경숙(이화여자대학교 환경공학과) | Kyung-suk Cho (Dept. of Environemntal Science and Engineering, Ewha Womans University)
  • 이은영(수원대학교 환경에너지공학과) | Eun Young Lee (Dept. of Environmental and Energy Engineering, The University of Suwon) Corresponding author