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Dye Decomposition in Seawater using Electro-Fenton Reaction

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한국환경과학회지 (Journal of Environmental Science International)
한국환경과학회 (The Korean Environmental Sciences Society)
초록

To increase electrolysis performance, the applicability of seawater to the iron-fed electro-Fenton process was considered. Three kinds of graphite electrodes (activated carbon fiber-ACF, carbon felt, graphite) and dimensionally stable anode (DSA) electrode were used to select a cathode having excellent hydrogen peroxide generation and organic decomposition ability. The concentration of hydrogen peroxide produced by ACF was 11.2 mg/L and those of DSA, graphite, and carbon felt cathodes were 12.9 ~ 13.9 mg/L. In consideration of durability, the DSA electrode was selected as the cathode. The optimum current density was found to be 0.11 A/cm2, the optimal Fe2+ dose was 10 mg/L, and the optimal ratio of Fe2+ dose and hydrogen peroxide was determined to be 1:1. The optimum air supply for hydrogen peroxide production and Rhodamine B (RhB) degradation was determined to be 1 L/min. The electro-Fenton process of adding iron salt to the electrolysis reaction may be shown to be more advantageous for RhB degradation than when using iron electrode to produce hydrogen peroxide and iron ion, or electro-Fenton reaction with DSA electrode after generating iron ions using an iron electrode.

목차
Abstract
1. 서 론
2. 재료 및 방법
    2.1. 반응기와 실험방법
    2.2. 분석 및 측정방법
3. 결과 및 고찰
    3.1. 과산화수소 생성과 Rhodamine B 분해에 대한 음극의 영향
    3.2. 과산화수소 생산과 Rhodamine B 분해에 대한 전류밀도의 영향
    3.3. 과산화수소 생산과 Rhodamine B 분해에 대한 Fe2+농도의 영향
    3.4. 과산화수소 생산과 Rhodamine B 분해에 대한 공기 공급량의 영향
    3.5. 최적조건에서 OH 라디칼 생성 비교 및 철 전극 전기-펜톤 공정과의 비교
4. 결 론
REFERENCES
저자
  • 김동석(대구가톨릭대학교 환경과학과) | Dong-Seog Kim (Department of Environmental Science, Catholic University of Daegu)
  • 박영식(대구대학교 창조융합학부) | Young-Seek Park (Division of Liberal Studies, Daegu University) Corresponding author