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혼합물 실험계획법을 이용한 OH라디칼 최적 생성을 위한 삼성분 전극의 비율 선정 KCI 등재

Using Design of Mixture Experiments to Select the Ratio of a Three-Component Electrode for Optimal Generation of Hydroxyl Radicals

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한국환경과학회지 (Journal of Environmental Science International)
한국환경과학회 (The Korean Environmental Sciences Society)
초록

The conventional development of multi-component electrodes is based on the researcher's experience and is based on trial and error. Therefore, there is a need for a scientific method to reduce the time and economic losses thereof and systematize the mixing of electrode components. In this study, we use design of mixture experiments (DOME)- in particular a simplex lattice design with Design Expert◯R program- to attempt to find an optimum mixing ratio for a three-component electrode for the high RNO degradation; RNO is an indictor of OH radical formation. The experiment included 12 experimental points with 2 center replicates for 3 different independent variables (with the molar ratio of Ru, Ti, Ir). As the Prob > F value of the ‘Quadratic’ model is 0.0026, the secondary model was found to be suitable. Applying the molar ratio of the electrode components to the corrected response model results is an RNO removal efficiency (%) = 59.89 × [Ru] + 9.78 × [Ti] + 67.03 × [Ir] + 66.38 × [Ru] × [Ir] + 132.86 × [Ti] × [Ir]. The R2 value of the equation is 0.9374 after the error term is excluded. The optimized formulation of the ternary electrode for an high RNO degradation was acquired when the molar ratio of Ru 0.100, Ti 0.200, Ir 0.700 (desirability d value, 1).

목차
Abstract
1. 서 론
2. 재료 및 방법
    2.1. 혼합물 실험계획
    2.2. 분석 및 측정방법
3. 결과 및 고찰
    3.1. 혼합물 반응표면분석
    3.2. 공정 최적화
4. 결 론
REFERECNCES
저자
  • 박영식(대구대학교 자유전공학부) | Young-Seek Park (Division of Liberal Studies, Daegu University) Corresponding author