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Lu3Al5-xGaxO12:Ce3+,Cr3+ 형광체의 결정구조 분석 및 잔광성 발광 특성 KCI 등재 SCOPUS

Crystal Structure Refinement and Persistent Luminescence Properties of Lu3Al5-xGaxO12:Ce3+,Cr3+ Phosphors

김지원, 김영진
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한국재료학회지 (Korean Journal of Materials Research)
한국재료학회 (Materials Research Society Of Korea)
초록

Lu3Al5-xGaxO12:Ce3+,Cr3+ powders are prepared using a solid-state reaction method. To determine the crystal structure, Rietveld refinement is performed. The results indicate that Ga3+ ions preferentially occupied tetrahedral rather than octahedral sites. The lattice constant linearly increases, obeying Vegard’s law, despite the strong preference of Ga3+ for the tetrahedral sites. Increasing x led to a blue-shift of the Ce3+ emission band in the green region and a change in the emission intensity. Persistent luminescence is observed from the powders prepared with x = 2–3, occurring through a trapping and detrapping process between Ce3+ and Cr3+ ions. The longest persistent luminescence is achieved for x = 2; its lifetime is at least 30 min. The findings are explained using crystal structure refinement, crystal field splitting, optical band gap, and electron trapping mechanism.

키워드
Lu3Al5O12garnetpersistent luminescenceafterglowphosphor
목차
Abstract
1.서 론
2. 실험 방법
3. 결과 및 고찰
4. 결 론
References
저자
  • 김지원(경기대학교 신소재 공학과) | Jiwon Kim (Department of Advanced Materials Engineering, Kyonggi University)
  • 김영진(경기대학교 신소재 공학과) | Young Jin Kim (Department of Advanced Materials Engineering, Kyonggi University) Corresponding author