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Break Point Chlorination (BPC) Characteristics for Heavy Metals Removal in Plating Wastewater Treatment

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한국환경과학회지 (Journal of Environmental Science International)
한국환경과학회 (The Korean Environmental Sciences Society)
초록

In this research, heavy metals and T-P removal characteristics of plated wastewater are derived using BPC(Break Point Chlorination) process. AA sedimentation pond outflow(Influence) was evaluated for the removal efficiency of heavy metal(Ni) and T-P at a reaction time of 25 minutes by NaOCl input volume(9, 11, 13 and 15 mL). In the case, the higher the NaOCl input volumes, the higher the ORP values were maintained and the higher the removal efficiency tended to be. On the other hand, T-P was judged to have a low relationship between the ORP value and the removal efficiency. In addition, the efficiency of removal heavy metals and T-P in the plated wastewater by injecting 10 mL, 15 mL, 20 mL and 25 mL NaOCl, increased as the amount of NaOCl injected increased, the amount of NaOH input for pH increased. It was found that suspended solid in effluence also increased. It was also observed that the color of the plating wastewater changed from yellowish green to green to charcoal gray to black as the amount of NaOCl injected increased. Treatment characteristics of the reaction time, the longer the reaction time with the substance to be treated after the input of NaOCl, the more the heavy metal removal efficiency tended to increase. Through XRF analysis of the sludge, the constituents in the sludge such as NaCNO, CNCl, Na3PO4, CrO4, 2Na2CrO4 and 2NaNO3 will be analyzed in detail, and the mechanisms of the reaction between the plated wastewater and the complex compound will be elucidated.

목차
Abstract
1. 서 론
2. 연구방법
    2.1. 실험재료
    2.2. 실험장치 및 방법
3. 결과 및 고찰
    3.1. NaOCl 주입량(초기 일시주입)에 따른 도금폐수의처리 특성
    3.2. NaOCl 주입 후 반응시간에 따른 도금폐수의 처리특성
4. 결 론
REFERENCES
저자
  • 정병길(동의대학교 환경공학과) | Byung-Gil Jung (Department of Environmental Engineering, Dong-Eui University, Busan 47340, Korea)
  • 이승원(동의대학교 환경공학과) | Seung-Won Lee (Department of Environmental Engineering, Dong-Eui University, Busan 47340, Korea)
  • 윤권감(동의대학교 환경공학과) | Kwon-Gam Yun (Department of Environmental Engineering, Dong-Eui University, Busan 47340, Korea)
  • 정진희(동아대학교 환경공학과) | Jin-Hee Jung (Department of Environmental Engineering, Dong-A University, Busan 49315, Korea)
  • 김정웅(국제기산(주)) | Jeong-Woong Kim (KookJeGiSan Co, Ltd., Busan 49486, Korea)
  • 최영익(동아대학교 환경공학과) | Young-Ik Choi (Department of Environmental Engineering, Dong-A University, Busan 49315, Korea) Corresponding author