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환원-산화 연계처리를 통한 니트로벤젠의 반응성 향상 및 무해화 연구 KCI 등재

Improving the Reactivity and Harmlessness of Recalcitrant Contaminants by Reduction-oxidation-linked Process

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한국환경과학회지 (Journal of Environmental Science International)
한국환경과학회 (The Korean Environmental Sciences Society)
초록

In this study, the applicability of reduction-oxidation-linked treatment was evaluated for nitrobenzene and a by-product by analyzing the reaction kinetics. Nitrobenzene showed very low reactivity to persulfate that was activated using various methods. Nitrobenzene effectively reacted through the reduction process using Zero-Valent Iron (ZVI). However, aniline, a toxic substance, was produced as a by-product. Reduction-oxidation-linked treatment is a method that can allow the oxidative degradation of aniline after reducing nitrobenzene to aniline. The experimental results show improved reactivity and complete decomposition of the by-product. Improved reactivity and decomposition of the by-product were observed even under conditions in which the reduction-oxidation reaction was induced simultaneously. No activator was injected for persulfate activation in the process of reducing oxidant linkage, and the activation reaction was induced by ferrous iron eluted from the ZVI. This indicates that this method can be implemented relatively simply.

목차
Abstract
1. 서 론
2. 재료 및 실험방법
    2.1. 재료
    2.2. 실험 방법
    2.3. 분석방법
3. 결과 및 고찰
    3.1. 니트로벤젠의 산화, 환원 분해특성
    3.2. 환원부산물의 발생 및 분해특성
    3.3. 환원-산화 연계처리를 통한 무해화 효과
    3.4. 환원-산화 동시반응에 의한 니트로벤젠 및 부산물분해
4. 결 론
REFERENCES
저자
  • 권희원(안동대학교 환경공학과) | Hee-Won Kwon (Department of Environmental Engineering, Andong National University, Andong 36729, Korea)
  • 황인성(부산대학교 토목환경공학과) | Inseong Hwang (Department of Civil and Environmental Engineering, Pusan National University, Busan 46241, Korea)
  • 김영훈(안동대학교 환경공학과) | Young-Hun Kim (Department of Environmental Engineering, Andong National University, Andong 36729, Korea) Corresponding author