논문 상세보기

아연-공기 전지용 음극재의 자가방전 억제 효과 KCI 등재 SCOPUS

Effect of Zinc Based Anodes on Self-Discharge Behavior for Zinc-Air Batteries

  • 언어KOR
  • URLhttps://db.koreascholar.com/Article/Detail/404047
구독 기관 인증 시 무료 이용이 가능합니다. 4,000원
한국재료학회지 (Korean Journal of Materials Research)
한국재료학회 (Materials Research Society Of Korea)
초록

For zinc-air batteries, there are several limitations associated with zinc anodes. The self-discharge behavior of zincair batteries is a critical issue that is induced by corrosion reaction and hydrogen evolution reaction (HER) of zinc anodes. Aluminum and indium are effective additives for controlling the hydrogen evolution reaction as well as the corrosion reaction. To enhance the electrochemical performances of zinc-air batteries, mechanically alloyed Zn-Al and Zn-In materials with different compositions are successfully fabricated at 500rpm and 5h milling time. Investigated materials are characterized by X-ray diffractometer (XRD), field emission scanning electron microscope (FE-SEM), and energy dispersive spectrometer (EDS). Alloys are investigated for the application as novel anodes in zinc-air batteries. Especially, the material with 3 wt% of indium (ZI3) delivers 445.37 mAh/g and 408.52 mAh/g of specific discharge capacity with 1 h and 6 h storage, respectively. Also, it shows 91.72 % capacity retention and has the lowest value of corrosion current density among attempted materials.

목차
Abstract
1. 서 론
2.실 험
    2.1 전해질 제조
    2.2 아연 음극재 제조
    2.3 전지 조립
    2.4 측정 및 분석
3. 결과 및 고찰
    3.1 재료 특성
    3.2 자가방전 거동
    3.3 부식 거동
4.결 론
Acknowledgement
References
저자
  • 정민서(한라대학교 공과대학 신소재화학공학과) | Min Seo Jung (Department of Advanced Materials & Chemical Engineering, College of Engineering, Halla University)
  • 조용남(한라대학교 공과대학 신소재화학공학과) | Yong Nam Jo (Department of Advanced Materials & Chemical Engineering, College of Engineering, Halla University) Corresponding author