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석탄 비산재로부터 합성된 제올라이트의 암모니아의 흡착용량 및 파과특성 KCI 등재

Ammonia Adsorption Capacity and Breakthrough Curve of Zeolitic Materials Synthesized from Coal Fly Ash

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한국환경과학회지 (Journal of Environmental Science International)
한국환경과학회 (The Korean Environmental Sciences Society)
초록

A zeolite material with a Si/Al molar ratio of 1.2 was synthesized by changing the NaOH/CFA ratio of coal fly ash (CFA) via a fusion/hydrothermal reaction in the HD thermal power plant. The change in the crystal structure of the zeolite was confirmed using XRD and SEM, and the ammonia adsorption capacities of the synthesized zeolitic materials and a commercial zeolite (Na-A zeolite) were analyzed via an ammonia temperature-programmed desorption (NH3-TPD) process. The SEM and XRD results revealed out the zeolitic materials from the coal fly ash maintained a hexagonal Linde-type crystal structure similar to that of Na-A zeolite, but the crystallinity of the synthesized zeolitic material was reduced due to impurities. The NH3 adsorption capacity, determined from the NH3-TPD analysis of was 1.122 mmol/g of the synthesized zeolitic material, which was lower than the NH3 adsorption capacity of the Na-A zeolite.

목차
Abstract
1. 서 론
2. 재료 및 방법
    2.1. 흡착제 제조
    2.2. 흡착제의 물리화학적 특성 분석
    2.3. 실험 장치 및 방법
    2.4. 암모니아 승온 탈착 실험
3. 결과 및 고찰
    3.1. 석탄비산재의 특성 분석
    3.2. 제올라이트 흡착제 제조
    3.3. 암모니아 가스 파과곡선
    3.4. 암모니아 흡착량 평가
    3.5. 흡착제의 NH3-TPD 평가
4. 결 론
감사의 글
REFERENCES
저자
  • 박종원(부산가톨릭대학교 환경행정학과) | Jong-Won Park (Department of Environmental Adminstration, Catholic University of Pusan, Busan 46252, Korea)
  • 이창한(부산가톨릭대학교 환경행정학과) | Chang-Han Lee (Department of Environmental Adminstration, Catholic University of Pusan, Busan 46252, Korea) Corresponding author