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내부 도핑 법에 의한 Cu 도핑 Cu:ZnSe 양자점의 수계 합성 및 발광 특성 KCI 등재

Aqueous Synthesis and Luminescent Characteristics of Cu:ZnSe Quantum Dots by Internal Doping Method

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한국분말야금학회지 (Journal of Korean Powder Metallurgy Institute)
한국분말재료학회(구 한국분말야금학회) (Korean Powder Metallurgy Institute)
초록

Cu-doped ZnSe quantum dots were successfully synthesized in an aqueous solution using an internal doping method. The effects of ligand type, CuSe synthesis temperature, and heating time on Cu-doped ZnSe synthesis were systematically investigated. Of MPA, GSH, TGA, and NAC used as ligands, MPA was the optimal ligand as determined by PL spectrum analysis. In addition, the emission wavelength was found to depend on the synthesis temperature of the internal doping core of CuSe. As the temperature increased, the doping of Cu2+ was enhanced, and the emission wavelength band was redshifted; accordingly, the emission peaks moved from blue to green (up to 550 nm). Thus, the synthesis of Cu:ZnSe using internal doping in aqueous solutions is a potential method for ecomanufacturing of colortuned ZnSe quantum dots for display applications.

목차
Abstract
1. 서 론
2. 실험방법
    2.1 시료
    2.2 표면도핑 Cu:ZnSe 나노 입자 합성
    2.3 내부도핑 Cu:ZnSe 나노 입자 합성
    2.4 특성 분석
3. 결과 및 고찰
    3.1 도핑 공정 따른 Cu:ZnSe 특성
    3.2 리간드 종류에 따른 특성
    3.3 CuSe 전구체 가열 온도의 영향
    3.4 Cu:ZnSe 합성 시간의 영향
4. 결 론
References
저자
  • 백금지(성신여자대학교 미래응용과학학과) | Geum Ji Back (Department of Next Generation Applied Sciences, Sungshin Women’s University, Seoul 01133, Republic of Korea)
  • 홍현선(성신여자대학교 미래응용과학학과, 성신여자대학교 청정융합에너지공학과) | Hyun Seon Hong (Department of Next Generation Applied Sciences, Sungshin Women’s University,Department of Environment & Energy Engineering, Sungshin Women’s University) Corresponding author