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조성 및 실록산 분자 구조에 따른 전자 패키징용 에폭시 기반 실록산/실리카 복합체의 물성 변화 분석 KCI 등재

Epoxy-Based Siloxane/Silica Composites for Electronic Packaging by Composition and Molecular Structure of Siloxane, and Analysis of Changes in Properties

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한국분말야금학회지 (Journal of Korean Powder Metallurgy Institute)
한국분말재료학회(구 한국분말야금학회) (Korean Powder Metallurgy Institute)
초록

Epoxy-based composites find extensive application in electronic packaging due to their excellent processability and insulation properties. However, conventional epoxy-based polymers exhibit limitations in terms of thermal properties and insulation performance. In this study, we develop epoxy-based siloxane/silica composites that enhance the thermal, mechanical, and insulating properties of epoxy resins. This is achieved by employing a sol–gelsynthesized siloxane hybrid and spherical fused silica particles. Herein, we fabricate two types of epoxy-based siloxane/ silica composites with different siloxane molecular structures (branched and linear siloxane networks) and investigate the changes in their properties for different compositions (with or without silica particles) and siloxane structures. The presence of a branched siloxane structure results in hardness and low insulating properties, while a linear siloxane structure yields softness and highly insulating properties. Both types of epoxy-based siloxane/silica composites exhibit high thermal stability and low thermal expansion. These properties are considerably improved by incorporating silica particles. We expect that our developed epoxy-based composites to hold significant potential as advanced electronic packaging materials, offering high-performance and robustness.

목차
1. Introduction
2. Experimental
    2.1 사용 재료
    2.2 에폭시 기반 실록산 하이브리드 수지 합성
    2.3 에폭시 기반 실록산/실리카 복합체 제작
    2.4 특성평가
3. Results and Discussion
    3.1 에폭시 기반 실록산/실리카 복합체 제작
    3.2 에폭시 기반 실록산/실리카 복합체의 기계적 특성
    3.3 에폭시 기반 실록산/실리카 복합체의 열적 특성
    3.4 에폭시 기반 실록산/실리카 복합체의 절연 특성
4. Conclusion
Acknowledgement
저자
  • 장준호(한국과학기술원 신소재공학과, 한국과학기술원 웨어러블 플랫폼소재 기술센터) | Junho Jang (Department of Materials Science and Engineering, Korea Advanced Institute of Science and Technology (KAIST), Daejeon 34141, Republic of Korea, Wearable Platform Materials Technology Center (WMC), KAIST, Daejeon 34141, Republic of Korea)
  • 강동준(한국전기연구원 전기재료연구본부 절연재료연구센터) | Dong Jun Kang (Insulation Materials Research Center, Electrical Materials Research Division, Electrotechnology Research Institute (KERI), Changwon 51543, Republic of Korea)
  • 임현균(한국전기연구원 전기재료연구본부 절연재료연구센터) | Hyeon-Gyun Im (Insulation Materials Research Center, Electrical Materials Research Division, Electrotechnology Research Institute (KERI), Changwon 51543, Republic of Korea) Corresponding Author