In-situ gamma spectrometer with mobile equipment can be used for rapid determination of radioactivity in the environment within a very short interval. 2”×2” NaI(Tl) scintillator are used to build a mobile radiation measurement system (called as Monitoring of Ambient Radiations of KAERI for Backpack, MARK-B3) with a signal processing unit, and GPS and interface units to a PC for wireless controlling system. Development of the survey system is to measure ambient gamma-ray spectrometry for estimating ground radioactivity and radiation dose in the environment. The ambient dose rate is estimated using G-factor method. For determination of G-factor, we conducted MCNP simulations in assumptions of various incident photons into the detector system. And the scintillator was exposed to Cs-137 source in the range of 1- 300 mGy/hr. Calculated dose rates for different simulation results were compared to the irradiated dose rate to derive correction factor of G-factor. To evaluate performance of the MARK-B3, in-situ gamma spectrometry was conducted in Jeju island.