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Galvanic Corrosion Behavior of Copper Canister KCI 등재 SCOPUS

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방사성폐기물학회지 (Journal of the Korean Radioactive Waste Society)
한국방사성폐기물학회 (Korean Radioactive Waste Society)
초록

In this study, we investigated the suppression of the corrosion of cast iron in a copper–cast iron double-layered canister under local corrosion of the copper layer. The cold spray coating technique was used to insert metals with lower galvanic activity than that of copper, such as silver, nickel, and titanium, between the copper and cast iron layers. Electrochemically accelerated corrosion tests were performed on the galvanic specimens in KURT groundwater at a voltage of 1.0 V for a week. The results revealed that copper corrosion was evident in all galvanic specimens of Cu–Ag, Cu–Ni, and Cu–Ti. By contrast, the copper was barely corroded in the Cu–Fe specimens. Therefore, it was concluded that if an inactive galvanic metal is applied to the areas where local corrosion is concerned, such as welding parts, the disposal canister can overcome local or non-uniform corrosion of the copper canister for long periods.

목차
1. Introduction
2. Experiment
    2.1 Test Specimens
    2.2 Electrochemical Test
    2.3 Surface Observations
3. Experimental Results and Discussions
    3.1 Corrosion Potentials
    3.2 Electrostatic Voltammetry Test
    3.3 Morphological Observations
4. Conclusions
Conflict of Interest
Acknowledgements
REFERENCES
저자
  • Minsoo Lee(Korea Atomic Energy Research Institute, 111, Daedeok-daero 989beon-gil, Yuseong-gu, Daejeon 34057, Republic of Korea) Corresponding author
  • Junhyuk Jang(Korea Atomic Energy Research Institute, 111, Daedeok-daero 989beon-gil, Yuseong-gu, Daejeon 34057, Republic of Korea)
  • Jin Seop Kim(Korea Atomic Energy Research Institute, 111, Daedeok-daero 989beon-gil, Yuseong-gu, Daejeon 34057, Republic of Korea)