Efficient Li-ion transport in anode materials is paramount for electric vehicles (EVs) and energy storage systems. The rapid charging demands of EVs can lead capacity decay at high charging rate. To overcome this challenge, we focus on graphite geometric characteristics that effect to interparticle space. We interpret the correlation between the utilization of the electrode and the interparticle space where solvated Li-ion transports in liquid electrolyte. To introduce variability into this space, two main coke precursors, coal cokes and petroleum cokes, were prepared and further categorized as normal cokes and needle cokes. Manufactured graphite samples were observed with distinct geometric characteristics. In this study, investigates the impact of these geometric variations on electrochemical performance, emphasizing rate capability and cycle stability during fast charging. By analyzing the transport properties of electrochemical species within these graphite samples, we reveal the critical role of morphology in mitigating concentration polarization and side reaction, such as Li-plating. These findings offer promising contribution for the development of advanced anode materials, in fast-charging condition in Li-ion.

Correlation between graphite morphology and interparticle space affecting rate performance in Li-ion battery anodes
    Abstract
    1 Introduction
    2 Experiment
        2.1 Preparation of different cokes artificial graphite
        2.2 Materials and electrodes characterization
    3 Results and discussion
    4 Conclusions
    Acknowledgements 
    References

• Sung Hoon Lee(WCU Hybrid Materials Program, Department of Materials Science and Engineering, Research Institute of Advanced Materials, Seoul National University, Seoul 08826, Republic of Korea)
• Chong Rae Park(WCU Hybrid Materials Program, Department of Materials Science and Engineering, Research Institute of Advanced Materials, Seoul National University, Seoul 08826, Republic of Korea) Corresponding author