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In, Cr 동시 도핑에 따른 BiSbTe3 소재의 열전성능지수 증대 KCI 등재 SCOPUS

Thermoelectric Properties of In and Cr Co-Doped BiSbTe3

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한국재료학회지 (Korean Journal of Materials Research)
한국재료학회 (Materials Research Society Of Korea)
초록

We conducted a study on excessive doping of the Cr and In elements in Bi-Sb-Te materials satisfying the Hume- Rothery rule, and investigated the resulting electrical and thermal properties. From X-ray diffraction (XRD) results, we confirmed the formation of a single phase even with excessive doping. Through analysis of electrical properties, we observed the highest enhancement in electrical characteristics at y = 0.2, suggesting that the appropriate ratio of Bi-Sb significantly influences this enhancement. Using the Callaway-von Baeyer (CvB) model to assess scattering due to point defects, we calculated the experimental point defect scattering factor (ΓCvB.exp), which was notably high due to the substantial differences in volume and atomic weight between the substituted (Cr, In) and original (Bi, Sb) elements. Additionally, we conducted a single parabolic band (SPB) modeling analysis of materials with compositions y = 0.1 and 0.2, where, despite a decrease in densityof- states effective mass (md *) during the enhancement process from y = 0.1 to 0.2, a sharp increase in non-degenerate mobility (μ0) led to an 88 % increase in weighted mobility (μw). Furthermore, analyzing zT with respect to nH revealed a 51 % increase in zT at a composition of y = 0.2. This study confirmed a significant reduction in lattice thermal conductivity with the co-doping strategy, and with further compositional studies to improve electrical properties, we anticipate achieving high zT.

목차
Abstract
1. 서 론
2. 실험 방법
3. 결과 및 고찰
4. 결 론
Acknowledgement
References
<저자소개>
저자
  • 이창우(서울시립대학교 신소재공학과) | Changwoo Lee (Department of Materials Science and Engineering, University of Seoul, Seoul 02504, Republic of Korea)
  • 김준수(서울시립대학교 신소재공학과) | Junsu Kim (Department of Materials Science and Engineering, University of Seoul, Seoul 02504, Republic of Korea)
  • 허민수(서울시립대학교 신소재공학과) | Minsu Heo (Department of Materials Science and Engineering, University of Seoul, Seoul 02504, Republic of Korea)
  • 김상일(서울시립대학교 신소재공학과) | Sang-il Kim (Department of Materials Science and Engineering, University of Seoul, Seoul 02504, Republic of Korea) Corresponding author
  • 김현식(서울시립대학교 신소재공학과) | Hyun-Sik Kim (Department of Materials Science and Engineering, University of Seoul, Seoul 02504, Republic of Korea) Corresponding author