Supercapacitors, renowned for their high power density and rapid charge-discharge rates, are limited by their low energy density. This limitation has prompted the need for advanced electrode materials. The present study investigated reduced graphene oxide (rGO) in two distinct structures, as a film and as an aerogel, for use as supercapacitor electrodes. The rGO film, prepared by vacuum filtration and thermal reduction, exhibited a compact, lamellar structure, while the aerogel, synthesized through hydrothermal treatment, was a highly porous three-dimensional network. Electrochemical analyses demonstrated the aerogel’s superior performance, as shown by a specific capacitance of 121.2 F/g at 5 mV/s, with 94% capacitance retention after 10,000 cycles. These findings emphasize the importance of structural design in optimizing ion accessibility and charge transfer. They also demonstrate the potential of rGO aerogels for increasing the energy storage efficiency of advanced supercapacitor systems.

1. Introduction
2. Experimental Section
3. Results and Discussion
4. Conclusion
Funding
Conflict of Interest
Data Availability Statement
Author Information and Contribution
Acknowledgments
References

• Sunghee Choi(Department of Urban, Energy, and Environmental Engineering, Chungbuk National University, Chungdae-ro 1, Seowon-Gu, Cheongju, Chungbuk 28644, Republic of Korea)
• Seulgi Kim(Department of Urban, Energy, and Environmental Engineering, Chungbuk National University, Chungdae-ro 1, Seowon-Gu, Cheongju, Chungbuk 28644, Republic of Korea)
• Seojin Woo(Department of Urban, Energy, and Environmental Engineering, Chungbuk National University, Chungdae-ro 1, Seowon-Gu, Cheongju, Chungbuk 28644, Republic of Korea)
• Dongju Lee(Department of Urban, Energy, and Environmental Engineering, Chungbuk National University, Chungdae-ro 1, Seowon-Gu, Cheongju, Chungbuk 28644, Republic of Korea, Department of Advanced Materials Engineering, Chungbuk National University, Chungdae-ro 1, Seowon-Gu, Cheongju, Chungbuk 28644, Republic of Korea) Corresponding author