Germination of chili pepper seeds is critical for crop yield and resource utilization. A high germination rate increases yield and effectively reduces resource wastage. This study collected 450 macroscopic images of chili pepper seeds and constructed a dataset for deep learning training through standardized germination experiments. Six deep learning models were evaluated to improve the chili pepper seed classification accuracy and germination rate. After comparing the performance of the models, MobileNet_v2 performed the best, not only having the fewest number of parameters but also achieving a 98.89% accuracy and 97.82% F1 score. The model improved the original germination rate from 87.33% to 100% on the test set, significantly optimizing the seed selection process