Manganese dioxide, functioning as a cathode material for aqueous zinc-ion batteries (AZIBs), demonstrates a variety of benefits, such as elevated theoretical specific capacity, outstanding electrochemical performance, environmental compatibility, ample resource availability, and facile modification. These advantages make MnO2 one of the cathode materials that have attracted much attention for AZIBs. Nevertheless, manganese dioxide cathode in practical applications suffers from structural instability during the cycling process because of sluggish electrochemical kinetics and volume expansion, which hinder their large-scale application. Doping and compositing with conducting frameworks is an effective strategy for improving structural stability. Herein, homogeneously in situ growth of Yttrium-doped MnO2 nanorods on conductive reduced graphene oxide (Y-MnO2/rGO), were synthesized through a straightforward hydrothermal method. The Y-MnO2/rGO electrodes have an ultra-long cycle life of 179.2 mA h g− 1 after 2000 cycles at 1 A g− 1 without degradation. The excellent structural stability is attributed to the cooperative effect of yttrium doping and compositing with rGO, which is an effective approach to enhance the stability and mitigate the Jahn–Teller distortion associated with Mn ions.

Yttrium-doped MnO2rGO composites as cathode material for ultra-long cycle life aqueous zinc-ion battery
    Abstract
    1 Introduction
    2 Experimental section
        2.1 Synthesis of Y-MnO2rGO
        2.2 Material characterization
        2.3 Electrochemical measurements
    3 Results and discussion
    4 Conclusion
    Acknowledgements 
    References

• Tong Wei(Institute of Materials and Technology, Dalian Maritime University, Dalian 116026, China)
• Song Li(Institute of Materials and Technology, Dalian Maritime University, Dalian 116026, China) Corresponding author
• Taowei Xu(Institute of Materials and Technology, Dalian Maritime University, Dalian 116026, China)
• Luwei Zhou(Institute of Materials and Technology, Dalian Maritime University, Dalian 116026, China)
• Siyuan Yin(Institute of Materials and Technology, Dalian Maritime University, Dalian 116026, China)
• Zhongsheng Wen(Institute of Materials and Technology, Dalian Maritime University, Dalian 116026, China)
• Juncai Sun(Institute of Materials and Technology, Dalian Maritime University, Dalian 116026, China)