Demonstration study on the removal of sulfur compounds originating from wastewater treatment facilities using amorphous iron hydroxide-based desulfurizing agent
This study evaluated the field-scale performance of an amorphous iron hydroxide (Fe(OH)3)-based desulfurizing agent for the removal of sulfur-based odorous compounds emitted from wastewater treatment facilities, including equalization tanks and sludge dewatering unit facilities. Hydrogen sulfide (H2S), methyl mercaptan (MM), dimethyl sulfide (DMS), and dimethyl disulfide (DMDS), which account for over 60~80% of total odor impact in such facilities, were targeted in this research. A drytype adsorption system packed with porous amorphous Fe(OH)3 was installed at a wastewater treatment plant and operated continuously for 45 days. Odorous gas concentrations were measured before and after treatment using portable analyzers and gas chromatography-pulsed flame photometric detector (GC-PFPD). The desulfurizing agent demonstrated a high H2S removal efficiency of over 99.9%, even under high inlet concentrations exceeding 500 ppm. Physicochemical analyses including XRD, XRF, EDS and BET confirmed that the material was amorphous, possessed a high surface area (243.4 m2/g), and exhibited a mesoporous structure favorable for gas adsorption. Hysteresis observed in nitrogen adsorption isotherms indicated a bottleneck-shaped pore structure, which enhances adsorption of odorous gases and removal efficiency. Notably, the system maintained stable performance under varying humidity without significant degradation.