This study examined whether early-lead ECMWF Artificial Intelligence Forecasting System (AIFS) total column water (TCW) fields at +0, +6, and +12 h could be mapped to later-valid MIMIC-like total precipitable water (TPW) fields at +24 and +30 h using a U-Net. Separate models were developed from 59–60 six-hourly samples spanning 16 days. Equal-input references included +12 h persistence, linear-tendency extrapolation, and three-input linear regression, whereas target-lead AIFS fields were retained as information-advantaged operational references. In the six-field chronological model-selection subsets, the U-Net produced the lowest cosine-latitude-weighted MAE and RMSE among the examined equal-input references, with reductions of approximately 26–29% relative to the three-input linear regression. The frozen models were subsequently applied without refitting to one forecast initialized at 00 UTC on March 10, 2026, and similar relative improvements over the equal-input references were observed. Target-lead AIFS calibrations generally produced lower errors than the U-Net. The absolute TPW discrepancy increased with the magnitude of integrated vapor transport (IVT). These results suggest that early AIFS forecast trajectories contain useful information for later-valid MIMIC-like TPW mapping, although the short development period and single out-of-period case limit conclusions regarding broader temporal generalization.